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Windows could not startmissing or corrupt windows xp system32 config system

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Couple of things

1. You can buy 32GB and 64GB USB keys - your file should fit on one of these?

2. There are a number of really useful linux tools out there like: and

They can often fix problems including
They can even run windows under linux so you could either connect your external CD and burn a copy of the file or copy back onto the very large USB key.