Assuming that you are the IT Manager, I believe that you need to act, quickly and quietly.
First get out your company's policy manual. Talk to management and/or HR. If he is in violation of policy, let them know what your plan is, and make sure that it is approved. They may be reluctant to take it to law enforcement, however you may find that this character has been up to more than is apparent. You may want to contact a good consultant if you don't have a Informatio Security Departmentto do forensics work and maintain a solid 'chain of evidence'. Document EVERYTHING, ledaing up to the issue, and including the remedial actions taken.
Grab Iris as the firt poster recommended.
Is this guy a contractor? 'Inside' is not a clear definition. Laws and policies usually handle these 2 types slightly different, however, if it IS your company's code, he has no right to keep you from it, unless someone signed it over to him.
Once you have the passwords from Iris or other means, (babseball bats work, but they are a bit messy) login and audit for backdoors, modems on the LAN and 'extra' accounts. Come in early the next day, or stay late and change or delete them. ALL. Make sure that he has no recourse.
You may want to also review and secure other accounts from having similar rights, at least temporarily, so that he can't just 'borrow' an account form a nearby friend. Finally, restrict his rights or access accordingly.
If it is warranted, remedial action should come from HR, Management or law enforcement. I personally wouldn't trust him with ANY kind of access again. He has compromised your trust. He IS the weakest link. Goodbye.
If forced to work with him, I would scrutinize his activity withIris or Sessionwall for the duration of his tenure, and write it up so the next manager is aware.