www.ora.com is O'Reilly's website. They got their big start publishing Unix books, and continue that tradition. They have expanded the website to include on-line resources for all sorts of areas in IT, including PERL, Unix, Internet networking, etc.Check it out, but I suggest you try to remember your focus.
The best (only?) way to really get to learn Unix is to use it. Try to find a 2nd hand Unix box, with the O/S disks/tapes/CDs, and manuals. You only need a small one. Preferrably, it should be one of the reasonably "generic" Unixes, like AT&T System V ("five"). THE NCR boxes of the late 80's were the closest. If you can find one, it shouldn't cost you much, just don't expect any support.
An alternative is to build a small Intel powered computer and drop SUN Solaris 8 on it. You can pick it up as a free download from SUN's website, or purchase a whole kit cheap directly from them.
There are also, of course, all sorts of versions of Linux available. Linux is arguably just another variation of Unix, so playing with Linux will give you a taste of what Unix can be like.
With any of these, my advice is to stay away from the GUIs and MENU systems, as much as possible. Why? Because if you learn to manage a particular system through the menu system, then you have learned how to use that menu system. But your skills will not translate easily to a different system. On the other hand, if you learn from the command line, then your skills are MUCH MORE transferrable. So from a career perspective, you're much further ahead.
Good Luck.