There is a registry entry to set the user that logs in. If this is reset before you log out, it can "hide" your tracks.
The profile tells me this is not through the network. However, you can log into a machine via RAS. It is just a matter of mapping to the machine, just like you do through a full-time network connection.
Best bet to track it is to set up a security policy that tracks who logs in. However, he could potentially find this out if he was looking. If you want to do this, you probably do not want to announce it.
As far as email, it is unlikely that he is getting into your email, unless he is messing with security on the Exchange Server. If he really wanted to see your email, he could change your password and log in, but it is likely that you would catch him with this.
The registry can be hacked externally, so it is more likely that the logon is designed to either make you worry or to play practical jokes on you.
I would personally go to him directly and confront him about it. He will probably deny it, but if you do not reveal how you know, you will turn the power play around, as he will wonder how you knew. It might also be best to mention this with others around; the best opening is when he brings up a subject on the registry, security, etc. What ever you do, say it rather matter-of-fact.
I might also gather the security evidence first and then turn off the policy. If he breaks in again, you can be certain that he is searching for how you caughthim.
Gregory A. Beamer
MCP: +I, SE, SD, DBA