Password Audit is an essential component of overall security audit process. The tools you mentioned are primarily meant to work on the SAM file since the user information is stored in it.
In an AD environment, User account details are not stored in SAM. The Account details for the clients in AD are stored in %windir%\windowsDS\ntds.dit
since you are to perform the password audit in AD environ., I can think of two ways at this time:
a. Sniff the network for Windows Authentication exchanges n gather the password.
b. Attempt Brute-force attacks to check the strength of the passwords, the time a tool takes to crack the passwords etc.
Password and Audit policy used in AD environ, though, may depend on the business model of your organization but it should always be able to provide a good resistance to external (and internal) attacks.
Hope this helps.