Chris,
Is your Timesync OK now? You haven't done anything to that question yet... First of all make sure timesync is OK.
Second, is it a real move or did you just change the type? Changing a replica type from r/w to master takes, on a lan, just a few minutes. Never more than half an hour on a wan, since it doesn't change anything to the replica itself, it just changes a flag, and makes sure everyone is aware of that.
Check in NDSMGR32, right-click your partition, and select "Partition Continuity". This shows a grid, that you should read as "server x thinks of server y that..." his partition is OK, the last sync was at 15:32, and he's a master. For example.
If all servers agree on all partitions, everything is fine, and the problem is elsewhere. The only difference you should see is a few minutes on the last synchronisation. If they do not all agree, you can easily pick out the troubled guys. They should give a clear error (-6xx). If not, let us know, we can troubleshoot further.
One more thing: NDS traffic is low priority, so it will as good as never bother data traffic.
Jim