Speaking only for myself, since SBS is so wizard-ized, I give my SBS setups 2 volumes, the system/Apps as one on RAID1, and the data on the other volume on RAID5 disk.
Your Server can hold and address all 8 drives on its RAID controller? A couple years ago, I would've said to use your 36-giggers in a RAID1 for the system/apps volume, but today I'm leaning toward telling you to nix the 36-giggers and just stick with a pair of the 72GB for the system/apps RAID1. I would then use the remaining 4x 72GB in a RAID5 for all if the dynamic data of SBS if I needed the effective 200GB for capacity. If I didn't think we would need all 200GB but could get away with 130GB, then I'd make a 3x 72GB RAID5 and put the last 72GB on the RAID bus as a hot spare.
My reasoning for nix'ing the 36GB is three-fold.
1) systems only get fatter, and although 36GB is enough today for SBS 2K3 as long as you're careful during the setup wizard to redirect all dynamic data, i.e. the exchange infostore, company data, user data, SQL server data (if you're using SBS Premium with SQL Server?), you never know what you may want to stuff on the system volume tomorrow so I'm beginning to make those larger than 36GB;
2) I'm concerned with the heat buildup of having 8x drives in the system, depending on the case design, drive spacing, and cooling;
3) 36GB drives will only get harder and harder to find replacements should you need to in the future, plus the pricing is such that you get better GB for the buck going to the 72GB and up. I'm using 72GB as the smallest hard drive I'll spec for a new server today.
Another possibility depending on your RAID controller, is that you can make a JBOD of all 6x 72GB disks, and create a RAID1+0 of whatever size you want (40GB, 50GB, whatever) for your system volume, and dedicate the remaining capacity as your RAID5. This gives you greater flexibility than being limited to whole disk increments with your system volume, and is another advantage to eliminating the 36GB drives.
One last thought re: the 36-giggers. If you're required to utilize the 36GB drives but don't want to be limited to a 36GB system volume, then you can create a RAID1 volume on the 36GB drives and use it for your swap file, TEMP directory, exchange logs, and/or SQL Server logs as these will all perform better on RAID1 but don't need to be taking up precious system volume capacity.
My two cents, understanding that may be all it's worth.