You have to first lig in as Administrator and then change from work group to Domain by following steps-
1. Log in as Administrator
2. See that the IP address of your laptop is in the same network as of your Domain Controller. If not, change the IP address ,for example if your domain controller has 192.1.2.1,then change your IP address to the corresponding network of the DC.(Remember the classes).
3. Give the IP address of the DNS server in the prefered DNS box in the TCP/IP properties box
click ok.
4. Right click my computers, select properties, select Network Identification Tab, select properties, select Domain radio button and type the name of the Domain Controller and click ok.
5. Give the administrator name and password if asked.
6. click ok and you need to reboot the system.
You will notice the domain name in the LOG ON drop down box. Select it click ok.