Outlook xP and saving internet account settings

I presume you are talking about the POP3 settings. Short of taking screen shots and printing it out or saving to a jump drive to read on the new pc I'm not sure how you could export it.

I did check in the Registry and the information for Outlook pop3 settings are all there in Binary form. Don't know if you could export those keys and import into the Registry of the other PC. Make sure you export both registry for back up before doing anything.

If you have a windows xp machine you could try the files and setting transfer wizard.
That usually transfers settings for most ms apps.