Nancy,
I went back to my Outlook program to dig into this further for you. Mine is not OL2000 but the process I followed may be very similar to yours or at least give you the direction to the solution. I entered a recipient's name as a Value to afield property box. Here's how to do it. Get to the form in design mode, you will see Message, P.2, P.3 ...Properties, Actions tabs. Click on To box, not the To button, but the field which will contain the destination recipient. This box should now have a highlight around it with little squares allowing you to resize the box. If not then click on another tab (properties, actions) and come back to the Message tab and try again. Now that it's highlighted, Right-click on it and select properties or go to the top menu (file edit etc) and select Form, then Properties. A box will open with Display, Value and Validation. Under Display, the Name will say To. The next tab, Value, should allow you to select a recipient name for this box. Hope it works the same for you.
Gary