More information is needed. The router's function in life to to deliver the packets to the correct network segment (VLAN) or another network altogther (ie. 172.16 to 192.168). What is your DSL modem hooked into to...a switch, one pc? What is behind your router (what kind of router)?
The simplest way is to add static routes in the routers configuration reference the two routing points. Give the interfaces on the router an ip address from each respective network and then set the gateway address of the pc to be that interface on the router.