This will depend ALOT on how the RAID array was set up, and on which controller you are using.
I'll describe the process I used with a PowerEdge Raid Controller (DELL).
When the array is first set up, I used 5 20 gig disks. This gave us 80 Gigs of physically available disk space (+20 for the striping) I set up the logical array to show several hundred Gigs, I believe it was 180 Gigs. When I installed Netware, I had a partition that was 180 Gigs, however, the defined partitions were only 80 Gigs. The Raid controller fooled Netware into thinking that I actually had more space than I did, and it kept track of when and where things went on the hard drives. When I added another 20 Gig drive, the logical array grew to 100 Gogs, and I simply assigned a new partition of 20 Gigs and added it to the current 80 on the server.
My advice would be to make sure you have 2 backups, and test them both, before you start. This has alot of variables, so you will likely see something different that I did. Keep in mind though, that the Logical volume size can be anything, but you cannot use more space than is physically present (and remember the space is x-1 (5 20 gig drive means 80 gigs. ((5-1)*20=80))).
Kev