Kt7Raid

Want to connect 2 30Gig ATA100 7200rpm to Ide channel 3 master & slave also my udma66 13 Gig to Ide 4 CDr to Ide 1 CDRW to Ide 2 DVD to Ide 2 as slave Do not want to use Raid array. Can I still boot from one of the drives in Ide 3?
My sys 1 gig Athlon- Radeon 64meg ddr vivo – 524Meg 133 memory Intake and outtake large Case Fans as well as the cooler on cpu (home built machine) 13 gig Hardrive ata66 is Windows ME and full of programs