Hi Matt,
First, you can check the actual NIC at the manufacturer's site if you don't have the documentation handy. There you should be able to find out what type of card you have and its capabilities as well as its latest drivers.
Second, you cantry one of several sites that measure bandwidth speed from a PC such as:
http://bandwidthplace.com/speedtest/
(remove any spaces from the pasted URL)
The tests will only be of the top speed that can be acheived to that site which will be based on the slowest component between you and them.
If speed is an issue on the pc, please make sure that only the protocols needed are installed as too many protocols can slow down a connection. Also, try changing the connection at the hub(s) if any, because some may not be capable of 100 due to manufacture specifications or due to failure. Please post a comment with more information if necessary so we can give you more information.
HTH