Win2k clients automatically sync with the time server at logon and every 8 hrs afterwards.
You may need to sync your DC with an external time source.
The Microsoft documentation about the Net Time /setsntp command says that you can specify a list of servers in the command. And you can, but with a trick: Enclose the list in quotation marks, and separate server names with a space. For example, to tell your server to look for the time first at www.acme.com and then, if necessary, at www.apex.com, you'd type
net time /setsntp:"www.acme.com www.apex.com"
Here are a few that you can use:
tick.usno.navy.mil at 192.4.41.40
tock.usno.navy.mil at 192.5.41.41
ntp2.usno.navy.mil at 192.5.41.209
After you configure the time service to use the above time servers, you can test their operation by typing the following:
net stop w32time
to stop Windows Time Service. You can then try out your time source by typing
w32tm -once
to set the time from the time source just once (W32tm's default is to update the time regularly). The command spits out about a page of cryptic output; when the command succeeds, one of the lines will read Recv'ed from server 48 Bytes.... When you're finished, don't forget to type
net start w32time
to restart the time service.
For more help see http://www.windows2000faq.com/Articles/Index.cfm?ArticleID=14943