Look at the Flow Chart here to Fault Find
http://www.fonerbooks.com/power.htm
While it is possible to short out two pins on the ATX Connector on the PS's to check the Actual Voltages coming out of the unit unless you know what you are doing it's very difficult to actually do it safely and as we do not know which type of Power Supply that you have the directions are different.
Anyway the Voltages tell you very little under a Static Test without Load and it's very difficult to do Current Tests so that you know if the PS is actually working.
There are at least 3 Power Rails in every Power Supply with different voltages and currents 3.5, 5 and 12 V DC and all need to work to get the computer to start.
If Jacky's suggestion doesn't work you should test the system with a [b]Known Good[/b] Power Supply. But if the M'Board, HDD's or RAM/CPU has been damaged you may destroy the test PS.
Col
[i]edited[/i] for clarity I hope. ;)