Change printers when pringing envelopes

Does anyone know if it is possible to change the printer Word prints envelopes on? I open the envelope pringing feature in Word and address my envelope, when I click on the print icon, it prints the the Windows default printer. I am on a network andwould like to print to our envelope printer but my default printer in Windows has to be set for a different printer. Is there a way in Word to pick a different printer just to print envelopes on?