Which to take first Network+ or A+?

IMO A+, because A+ (hardware and software) is the core knowledge that you need to have a basic idea of what the devices are, before you get to networking. Others may have a different opinion though.

In all actuality, you could take either, but I would lean towards the A+. It covers OS and hardware issues and touches on Networking basics. These basics and the hardware knowledge will be a good starting point for moving into Net+.

Additionally,if you don't already work in IT, it will most likely be easier to get an entry-level job as a technician with the A+. Most people getting a Net+ want it to add to their technician abilities, or as a foundation for a CCNA, MCSE or CNE. Looking back, I kind of wish I'd taken the Net+ now...may have made my other certs a little easier to get.

Good luck! You're embarking on a very interesting and exciting career path...I know I wouldn't trade it for anything. Well...except maybe being a rock star...or a football player....maybe a race car driver....or....

;)