I would venture to say it's an anomoly if the computer is logging on to the SBS 20003 domain and the domain has 25 CALS and all CALS are not in use provided that SBS 2003 is the only server in the domain.
From Microsoft: http://www.microsoft.com/windows2000/server/howtobuy/pricing/types.asp
Per Seat mode vs. Per Server mode for Client Access License (CAL) licensing
Per Seat mode Best where workstations frequently connect to multiple servers within your organization.
Can be applied to Windows 2000 Server, Windows 2000 Advanced Server, and Windows 2000 Datacenter Server.
Example: 100 workstations regularly connect to a Windows 2000 Server. Purchase 100 CALs.
Per Server mode Best where workstations infrequently connect to specific servers.
You may switch from Per Server to Per Seat mode once.
Can be applied to Windows 2000 Server, Windows 2000 Advanced Server, and Windows 2000 Datacenter Server.
Example: 300 workstations sporadically connect to 5 servers, with no more than 20 connections to any one server at a time. Purchase 100 CALs.
now if you are running W2K Pro workstations and the problem is with connecting to a W2K machine, they can only have 10 concurrent connections. its a built in limitation so they aren't used as servers except in a very small environment like a workgroup.