NTFS Master Drive and FAT32 Slave Drive

I just recently installed a Western Digital Caviar 120 gigabyte hard drive as the master with NTFS running Windows 2000 Professional Edition, replacing a Quantum Fireball 40 gig drive which was running Windows ME with FAT32, now set up as slave drive. No problems booting to W2K but now can’t see the slave drive. What is the best way to move or back up the apps and data from the original Win ME (slave)drive to the new W2K (master) drive? Any help appreciated. Thanks! GadgetMD