Web history tracking

The only way to do it without software is to stand behind him/her and write down every move they take. :)

Please post back if you have any more problems or questions.
If this information is useful, please mark as helpful. Thanks

Yes does make it a tad difficult, you could try netstat from the cmd prompt.
It is a tool for checking your network configuration and activity.
http://en.wikipedia.org/wiki/Netstat

Just to add all activity on a computer with regards to emails and internet is recorded in what's called an index.dat file,
http://www.acesoft.net/delete_index.dat_files.htm

to see these you'll need a tool such as index.dat viewer
http://www.acesoft.net/index.dat%20viewer/index.dat_viewer.htm