The w32time error is telling you that you do not have a sntp server configured.If you are on a network most routers are also sntp servers. The command: nettime /setsntp servername sets the timeserver. If you are not on the network you can set your system time and ignore this error.
The second error: from Microsoft knowledge base:
Event Message 3101: Unable to Read IO control Information from NBT Device
The information in this article applies to:
Microsoft Windows 2000 Professional
SYMPTOMS
When you use a Windows 2000-based computer, the following error may be logged in the Application event log after every reboot:
Event Type: Error
Event Source: perfctrs
Event Category: None
Event ID: 3101
Date: boot_date
Time: boot_time
User: N/A
Computer: SYSTEM
Description: Unable to read IO control information from NBT device.
CAUSE
This behavior can occur if the Windows 2000 Transmission Control Protocol/Internet Protocol (TCP/IP) performance counters (Perfctrs.dll) are attempting to extract input/output (I/O) control information from a network device, but no network device (network adapter, modem, and so on) is present.
This problem can also occur if the performance counters attempt to extract I/O control information, but the network stack has not completed loading. This is a timing issue and does not necessarily indicate a problem.
RESOLUTION
To resolve this problem, obtain the latest service pack for Windows 2000. For additional information, please see the following article in the Microsoft Knowledge Base:
Q260910 How to Obtain the Latest Windows 2000 Service Pack
NOTE : You can also install the Microsoft Loopback adapter on the computer to try and resolve this behavior.
STATUS
This problem was first corrected in Windows 2000 Service Pack 2.