Windows XP will install with no administrator password.
This allows any competent user to access the local administrator account and do whatever they want to the machines.
You need to set the local machines administrator accounts to a password that is not known to the users. Maybe someone else can advise you on a method to do this via logon scripts or group polocies.
Next you need to disable (or delete , second option) the local user accounts these users have been using or have created. You may want to initially disable them as they may have data stored under the local profile that you will have to maintain access to.
If the user has been using the local profile exclusively you can copy the local user profile to the domain user profile to transfer there documents and settings to their domain profile. This is why you should disable rather than delete the lcoal rpfoile. Otherwise their data will be gone and they will be even less appreciative of losing their local admin access.
Have them log on to windows under their domain account to create the profiles directories.
Restart the computer. Windows will not let you copy the profile of a recently access user.
Log on under an admin account, local administrator or a domain admin account.
Open System Properties, Advanced tab. Click on the settings button under "User Profiles.
Here you will see a list of all of the profiles stored on the computer , both domain and local.
Select the local profile of user you want to copy, shown as localmachine\username and click on the Copy to button.
Click on Browse and move to the Documents and Settings / Users (vista) folder auntil you have located the Domain Profile folder for the user. If the local username and the domain username is the same you will see two folders smithj and smithj.domainname the first would be the local profile you have already selected in the Systems Properties list. The second would be the domain profile folder you want to copy to. Higlight the folder and click on O.K.
Back in the Copy To window click on change and enter the users domain username. This will set the permissions on the user profile from the local account to the domain account so they can read nad write to the files after they are copied. Let windows complete the task.
A little long winded but I wanted to make sure I covered what is required to save their data before you deleted it all.